Remote sensing of aerosols at night with the CoSQM sky brightness data

Aerosol optical depth is an important indicator of aerosol particle properties and their associated radiative impacts. AOD determination is very important to achieve relevant climate modelling. Most remote sensing techniques to retrieve aerosol optical depth are applicable to daytime given the high level of light available. The night represents half of the time but in such conditions only a few remote sensing methods are available. Among these approaches, the most reliable are moon photometers and star photometers. In this paper, we attempt to fill gaps in the aerosol detection performed with the aforementioned techniques using night sky brightness measurements during moonless nights with the novel CoSQM, a portable, low-cost and open-source multispectral photometer. In this paper, we present an innovative method for estimating the aerosol optical depth using an empirical relationship between the zenith night sky brightness measured at night with the CoSQM and the aerosol optical depth retrieved during daytime from the AErosol Robotic NETwork

Long-term characterisation of the vertical structure of the Saharan Air Layer over the Canary Islands using lidar and radiosonde profiles: implications for radiative and cloud processes over the subtropical Atlantic Ocean

Every year, large-scale African dust outbreaks frequently pass over the Canary Islands (Spain). Here we describe the seasonal evolution of atmospheric aerosol extinction and meteorological vertical profiles on Tenerife over the period 2007–2018 using long-term micropulse lidar (MPL-3) and radiosonde observations. These measurements are used to categorise the different patterns of dust transport over the subtropical North Atlantic and, for the first time, to robustly describe the dust vertical distribution in the Saharan Air Layer (SAL) over this region. Three atmospheric scenarios dominate the aerosol climatology: dust-free (clean) conditions, the Saharan summer scenario (summer-SAL) and the Saharan winter scenario (winter-SAL). A relatively well-mixed marine boundary layer (MBL) was observed in the case of clean (dust-free) conditions; it was associated with rather constant lidar extinction coefficients (α) below 0.036 km−1 with minimum α (< 0.022 km−1) in the free troposphere (FT). The summer-SAL has been characterised as a dust-laden layer strongly affecting both the MBL (Δα = +48 % relative to clean conditions) and the FT. The summer-SAL appears as a well-stratified layer, relatively dry at lower levels (  % at the SAL’s base, where r is the water vapour mixing ratio) but more humid at higher levels compared with clean FT conditions (  % at 5.3 km), with a peak of α> 0.066 km−1 at ∼ 2.5 km. Desert dust is present up to ∼ 6.0 km, the SAL top based on the altitude of SAL's temperature inversion. In the winter-SAL scenario, the dust layer is confined to lower levels below 2 km altitude. This layer is characterised by a dry anomaly at lower levels (Δr∼ −38 % in comparison to the clean scenario) and a dust peak at ∼ 1.3 km height. Clean FT conditions were found above 2.3 km. Our results reveal the important role that both dust and water vapour play in the radiative balance within the summer-SAL and winter-SAL. The dominant dust-induced shortwave (SW) radiative warming in summer (heating rates up to +0.7 K d−1) is found slightly below the dust maximum. However, the dominant contribution of water vapour was observed as a net SW warming observed within the SAL (from 2.1 to 5.7 km) and as a strong cold anomaly near the SAL's top (−0.6 K d−1). The higher water vapour content found to be carried on the summer-SAL, despite being very low, represents a high relative variation in comparison to the very dry clean free troposphere in the subtropics. This relevant aspect should be properly taken into account in atmospheric modelling processes. In the case of the winter-SAL, we observed a dust-induced radiative effect dominated by SW heating (maximum heating of +0.7 K d−1 at 1.5 km, near the dust peak); both dust and atmospheric water vapour impact heating in the atmospheric column. This is the case of the SW heating within the SAL (maximum near the r peak), the dry anomaly at lower levels (Δr∼ −38 % at 1 km) and the thermal cooling (∼ 0.3 K d−1) from the temperature inversion upwards. Finally, we hypothesise that the SAL can impact heterogeneous ice nucleation processes through the frequent occurrence of mid-level clouds observed near the SAL top at relatively warm temperatures. A dust event that affected Tenerife on August 2015 is simulated using the regional DREAM model to assess the role of dust and water vapour carried within SAL in the ice nucleation processes. The modelling results reproduce the arrival of the dust plume and its extension over the island and confirm the observed relationship between the summer-SAL conditions and the formation of mid- and high-level clouds.The long-term meteorological sounding program has been supported by regular funds from AEMET. The long-term MPLNet program in Tenerife has been financed through R&D budgets from INTA and AEMET. AERONET sun photometers at Izaña have been calibrated within the AERONET Europe TNA, supported by the European Community Research Infrastructure Action under the FP7 ACTRIS (grant agreement no. 262254). This research has received support from the Institute of Physics Belgrade, through the grant by the Ministry of Education, Science, and Technological Development of the Republic of Serbia.Peer Reviewed"Article signat per 13 autors/es: África Barreto, Emilio Cuevas, Rosa D. García, Judit Carrillo, Joseph M. Prospero, Luka Ilić, Sara Basart, Alberto J. Berjón, Carlos L. Marrero, Yballa Hernández, Juan José Bustos, Slobodan Ničković, and Margarita Yela"Postprint (published version

Column water vapor determination in night period with a lunar photometer prototype

In this paper we present the preliminary results of atmospheric column-integrated precipitable water vapor (PWV) obtained with a new Lunar Cimel photometer (LC) at the high mountain Izaña Observatory in the period July–August 2011. We have compared quasi-simultaneous nocturnal PWV from LC with PWV from a Global Positioning System (GPS) receiver and nighttime radiosondes (RS92). LC data have been calibrated using the Lunar Langley method (LLM). We complemented this comparative study using quasi-simultaneous daytime PWV from Cimel AERONET (CA), GPS and RS92.The AERONET sun photometer at Izana has been calibrated within AERONET- ˜ EUROPE TNA supported by the European Community – Research Infrastructure Action under the FP7 “Capacities” specific program for Integrating Activities, ACTRIS grant agreement no. 262254

A 10-year characterization of the Saharan Air Layer lidar ratio in the subtropical North Atlantic

Particle extinction-to-backscatter ratio (lidar ratio) is a key parameter for a correct interpretation of elastic lidar measurements. Of particular importance is its determination for Saharan Air Layer mineral dust transported into the free troposphere over the North Atlantic region. The location of the two sun photometer stations managed by the Izaña Atmospheric Research Centre (IARC) on the island of Tenerife, and a decade of available micropulse lidar (MPL) data allows us to determine the lidar ratio under almost pure dust conditions. This result can be considered representative of the Saharan dust transported westward over the North Atlantic in the subtropical belt. Three different methods to calculate the lidar ratio have been used in this work: (1) using the inversion of sky radiance measurements from a sun/sky photometer installed at the Izaña Observatory (2373ma.s.l.) in free troposphere conditions; (2) the One-Layer method, a joint determination using a micro-pulse lidar sited at Santa Cruz de Tenerife sea-level station and photometric information considering a one layer of aerosol characterized by a single lidar ratio; (3) the Two-Layer method, a joint determination using the micro-pulse lidar and photometric information considering two layers of aerosol with two different lidar ratios. The One-Layer method uses data from a co-located photometer only at Santa Cruz de Tenerife, while the Two-Layer conceptual approach incorporates photometric information at two heights from the observatories of Izaña and Santa Cruz de Tenerife. The almost pure dust lidar ratio retrieval from the sun/sky photometer and from the Two-Layer method give similar results, with lidar ratios at 523nm of 49±6 sr and 50±11sr, respectively. These values obtained from a decade of data records are coincident with other studies in the literature reporting campaigns in the subtropical North Atlantic region. This result shows that the Two-Layer method is an improved conceptual approach compared to the single layer approach, that matches well the real lower troposphere structure. The Two-layer method is able to retrieve reliable lidar ratios and therefore aerosol extinction profiles, despite the inherent limitations of the elastic lidar technique. A lack of correlation between lidar ratio and Ångström exponent (α) indicates that the dust lidar ratio can be considered independent of dust size distribution in this region. This finding suggests that dust is, in most of atmospheric conditions, the predominant aerosol in the North Atlantic free troposphere.This work has been developed within the framework of the activities of the World Meteorological Organization (WMO) Commission for Instruments and Methods of Observations (CIMO) Izaña test bed for aerosols and water vapour remote sensing instruments. AERONET Sun photometers at Izaña have been calibrated within the AERONET Europe TNA, supported by the European Union’s Horizon 2020 research and innovation program under grant agreement no. 654109 (ACTRIS-2). The authors also acknowledge the AERONET team for their support, the Juan de la Cierva postdoctoral fellowship (JCI-2010-06097) from the Spanish Ministry of Science and Innovation, as well as the AMISOC proyect, CGL2011-24891, from the Spanish Plan for Research, Development and Innovation, which has partially supported the maintenance of the lidar at Santa Cruz de Tenerife. Our colleague Celia Milford improved the English of this paper

Characterization of an EKO MS-711 spectroradiometer: aerosol retrieval from spectral direct irradiance measurements and corrections of the circumsolar radiation [Discussion paper]

Spectral direct UV-Visible normal solar irradiance (DNI) measured with an EKO MS-711 spectroradiometer at the Izaña Atmospheric Observatory (IZO, Spain) has been used to determine aerosol optical depth (AOD) at several wavelengths (340, 380, 440, 500, 675 and 870 nm) between April and September 2019 that have been compared with synchronous AOD measurements from a reference Cimel-AERONET (Aerosol RObotic NETwork) sunphotometer. The EKO MS-711 has been calibrated at Izaña Observatory using the Langley-Plot method during the study period. Although this instrument has been designed for spectral solar DNI measurements, and therefore has a field of view (FOV) of 5° that is twice that recommended in solar photometry for AOD determination, the AOD differences compared against the AERONET Cimel reference instrument (FOV ∼ 1.2°), are fairly small. The comparison results between AOD Cimel and EKO MS-711 present a root mean square (RMS) of 0.013 (24.6 %) at 340, and 380 nm, and 0.029 (19.5 %) for longer wavelengths (440, 500, 675 and 870 nm). However, under relatively high AOD, near forward aerosol scattering might be significant because of the relatively large circumsolar radiation (CSR) due to the large EKO MS-711 FOV, resulting in a small but significant AOD underestimation in the UV range. The AOD differences decrease considerably when CSR corrections, estimated from LibRadtran radiative transfer model simulations, are performed, obtaining RMS of 0.006 (14.9 %) at 340 and 380 nm, and 0.005 (11.1 %) for longer wavelengths. The percentage of 2-minute synchronous EKO AOD–Cimel AOD differences within the World Meteorological Organization (WMO) traceability limits were ≥ 96 % at 500 nm, 675 nm and 870 nm with no CSR corrections. After applying the CSR corrections, the percentage of AOD differences within the WMO traceability limits increased to > 95 % for 380, 440, 500, 675 and 870 nm, while for 340 nm the percentage of AOD differences showed a poorer increase from 67 % to a modest 86 %.AERONET Sun photometers at Izaña have been calibrated within the AERONET Europe TNA, supported by the European Union Horizon 2020 research and innovation program under grant agreement no. 654109 (ACTRIS-2). This research benefited from the results of the project funding by MINECO RTI2018-097864-B-I00

Aerosol retrievals from the EKO MS-711 spectral direct irradiance measurements and corrections of the circumsolar radiation

Spectral direct UV–visible normal solar irradiance (DNI) has been measured with an EKO MS-711 grating spectroradiometer, which has a spectral range of 300–1100 nm, and 0.4 nm step, at the Izaña Atmospheric Observatory (IZO, Spain). It has been used to determine aerosol optical depth (AOD) at several wavelengths (340, 380, 440, 500, 675, and 870 nm) between April and September 2019, which has been compared with synchronous AOD measurements from a reference Cimel and Aerosol RObotic NETwork (AERONET) sun photometer. The EKO MS-711 has been calibrated at the Izaña Atmospheric Observatory by using the Langley plot method during the study period. Although this instrument has been designed for spectral solar DNI measurements, and therefore has a field of view (FOV) of 5∘ that is twice the recommended amount in solar photometry for AOD determination, the AOD differences compared to the AERONET–Cimel reference instrument (FOV ∼1.2∘) are fairly small. A comparison of the results from the Cimel AOD and EKO MS-711 AOD presents a root mean square (rms) of 0.013 (24.6 %) at 340 and 380 nm, and 0.029 (19.5 %) for longer wavelengths (440, 500, 675, and 870 nm). However, under relatively high AOD, near-forward aerosol scattering might be significant because of the relatively large circumsolar radiation (CSR) due to the large EKO MS-711 FOV, which results in a small but significant AOD underestimation in the UV range. The AOD differences decrease considerably when CSR corrections, estimated from libRadtran radiative transfer model simulations, are performed and obtain an rms of 0.006 (14.9 %) at 340 and 380 nm, and 0.005 (11.1 %) for longer wavelengths. The percentage of 2 min synchronous EKO AOD–Cimel AOD differences within the World Meteorological Organization (WMO) traceability limits were ≥96 % at 500, 675, and 870 nm with no CSR corrections. After applying the CSR corrections, the percentage of AOD differences within the WMO traceability limits increased to >95 % for 380, 440, 500, 675, and 870 nm, while for 340 nm the percentage of AOD differences showed a poorer increase from 67 % to a modest 86 %.This research has received funding from the European Union’s Horizon 2020 Research and Innovation Programme (grant no. 654109; ACTRIS-2). The funding from MINECO (grant no. CTM2015-66742-R) and Junta de Castilla y León (grant no. VA100P17) is also gratefully acknowledged. Much of this study has been performed in the framework of the WMO–CIMO Izaña test bed for aerosols and water vapour remote-sensing instruments and has been funded by the State Meteorological Agency of Spain (AEMET)

Recovering long-term aerosol optical depth series (1976–2012) from an astronomical potassium-based resonance scattering spectrometer

A 37-year long-term series of monochromatic aerosol optical depth (AOD) has been recovered from solar irradiance measurements performed with the solar spectrometer Mark-I, deployed at Izaña mountain since 1976. The instrument operation is based on the method of resonant scattering, which affords wavelength absolute reference and stability (long-term stability and high precision) in comparison to other instruments based purely on interference filters. However, it has been specifically designed as a reference instrument for helioseismology, and its ability to determine AOD from transmitted and scattered monochromatic radiation at 769.9 nm inside a potassium vapour cell in the presence of a permanent magnetic field is evaluated in this paper. Particularly, the use of an exposed mirror arrangement to collect sunlight as well as the Sun–laboratory velocity dependence of the scattered component introduces some important inconveniences to overcome when we perform the instrument's calibration. We have solved this problem using a quasi-continuous Langley calibration technique and a refinement procedure to correct for calibration errors as well as for the fictitious diurnal cycle on AOD data. Our results showed similar calibration errors retrieved by means of this quasi-continuous Langley technique applied in different aerosol load events (from 0.04 to 0.3), provided aerosol concentration remains constant throughout the calibration interval.The AERONET sun photometers at Izaña have been calibrated within AERONET-Europe TNA supported by the European Community-Research Infrastructure Action under the FP7 “Capacities” specific programme for Integrating Activities, ACTRIS grant agreement no. 262254. The GAW-PFR network for AOD at WMO-GAW global observatories has been implemented by the World Optical Depth Research and Calibration Center (WORCC). Mark-I operation was supported by the Spanish National Plan of Research and Development under grant no. AYA2012–17803

A new method for nocturnal aerosol measurements with a lunar photometer prototype

This paper presents the preliminary results of nocturnal Aerosol Optical Depth (τa) and Angström Exponent (α) obtained from a new lunar photometer prototype, trade name Cimel CE-318U. Due to the variation of the moon's illumination inherent to the lunar cycle, the typical Langley-plot Method used in solar photometry to calibrate these instruments cannot be applied. In this paper, we propose three different methods to carry out the lunar-photometer calibration. In order to validate the results, we have selected three events which encompass seven nights and ten days under different atmospheric conditions, including several saharan dust intrusions episodes. Method#1 is introduced in this work as a modification of the usual Langley Method.The Aeronet sunphotometer at Izana has been calibrated within ˜ AERONET-EUROPE TNA supported by the European Community – Research Infrastructure Action under the FP7 “Capacities” specific programme for Integrating Activities, ACTRIS Grant Agreement no. 262254

Spectral Aerosol Optical Depth retrievals by ground-based Fourier Transform Infrared spectrometry

Aerosol Optical Depth (AOD) and the Ångström Exponent (AE) have been calculated in the near infrared (NIR) and short-wave infrared (SWIR) spectral regions over a period of one year (May 2019–May 2020) at the high-mountain Izaña Observatory (IZO) from Fourier Transform Infrared (FTIR) solar spectra. The high-resolution FTIR measurements were carried out coincidentally with Cimel CE318-T photometric observations in the framework of the Aerosol Robotic Network (AERONET). A spectral FTIR AOD was generated using two different approaches: by means of the selection of seven narrow FTIR micro-windows (centred at 1020.90, 1238.25, 1558.25, 1636.00, 2133.40, 2192.00, and 2314.20 nm) with negligible atmospheric gaseous absorption, and by using the CE318-AERONET’s response function in the near-coincident bands (1020 nm and 1640 nm) to degrade the high-resolution FTIR spectra. The FTIR system was absolutely calibrated by means of a continuous Langley–Plot analysis over the 1-year period. An important temporal drift of the calibration constant was observed as a result of the environmental exposure of the FTIR’s external optical mirrors (linear degradation rate up to 1.75% month−1). The cross-validation of AERONET-FTIR databases documents an excellent agreement between both AOD products, with mean AOD differences below 0.004 and root-mean-squared errors below 0.006. A rather similar agreement was also found between AERONET and FTIR convolved bands, corroborating the suitability of low-resolution sunphotometers to retrieve high-quality AOD data in the NIR and SWIR domains. In addition, these results demonstrate that the methodology developed here is suitable to be applied to other FTIR spectrometers, such as portable and low-resolution FTIR instruments with a potentially higher spatial coverage. The spectral AOD dependence for the seven FTIR micro-windows have been also examined, observing a spectrally flat AOD behaviour for mineral dust particles (the typical atmospheric aerosols presented at IZO). A mean AE value of 0.53 ± 0.08 for pure mineral dust in the 1020–2314 nm spectral range was retrieved in this paper. A subsequent cross-validation with the MOPSMAP (Modeled optical properties of ensembles of aerosol particles) package has ensured the reliability of the FTIR dataset, with AE values between 0.36 to 0.60 for a typical mineral dust content at IZO of 100 cm−3 and water-soluble particle (WASO) content ranging from 600 to 6000 cm−3. The new database generated in this study is believed to be the first long-term time series (1-year) of aerosol properties generated consistently in the NIR and SWIR ranges from ground-based FTIR spectrometry. As a consequence, the results presented here provide a very promising tool for the validation and subsequent improvement of satellite aerosol products as well as enhance the sensitivity to large particles of the existing databases, required to improve the estimation of the aerosols’ radiative effect on climate.This study has been performed thanks to regular funds from the State Meteorological Agency of Spain (AEMET) to the World Meteorological Organization (WMO) Commission for Instruments and Methods of Observations (CIMO) Izaña Testbed for Aerosols and Water Vapor Remote Sensing Instruments, dedicated resources from SIELTEC S.L., and the European Community Research Infrastructure Action under the FP7 ACTRIS grant, agreement no. 262254. The authors also acknowledge the support from the Ministerio de Economía y Competitividad from Spain through the project INMENSE (CGL2016-80688-P) and Izaña staff for maintaining the instrumentation, thus ensuring the quality of the data

A new zenith looking narrow-band radiometer based system (ZEN) for dust Aerosol Optical Depth monitoring

This study presents a new zenith looking narrow-band radiometer based system (ZEN), conceived for dust aerosol optical depth (AOD) monitoring. Our results suggest that ZEN is a suitable system to fill the current observational gaps and to complement observations performed by sun-photometer networks in order to improve mineral dust monitoring in remote locations.AERONET sun photometers at Izaña have been calibrated within the AERONET Europe TNA, supported by the European Community-Research Infrastructure Action under the FP7 15 ACTRIS grant agreement no. 262254